Hydrogeninduced cracking hic in steel is a risk problem when steels are charged with hydrogen in service as in various hydrogen sulfide environments like sour oil and gas wells and some power plants. When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory. Stress corrosion cracking international institute of. Hydrogen embrittlement embrittlement is a phenomenon that causes loss of ductility in a material, thus making it brittle. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Hightemperature hydrogen attack is also referred to as hot hydrogen attack or decarburization. Transgranular stress corrosion cracking an overview.
In the case of hydrogen embrittlement, the hydrogen. Occurrence of the transgranular and intergranular hydrogenassisted cracking in the steels is assisted by 1 an increase in the hydrogenaffected zone associated with presence of. Also high strength structural steels which are welded are exposed to a certain hydrogen pickup which means a risk at fracture and blistering. The phenomenon of plasticityrelated hydrogen induced cracking can be illustrated by experimental results on a highpurity 5% ni steel tested in 0. Defects hydrogen cracks in steels identification twi. Decrease in the density and size of ductile features tear. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Material damage due to hydrogen embrittlement and stress corrosion cracking can be classed as cases which cannot be clari. Intergranular fracture and corrosion occur for a wide variety of reasons. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, v characterization of oxide film on stainless steel by multilateral surface analyses yohei murayama1, tomonori satoh1, shunsuke uchida1. The interaction of corrosion fatigue and stresscorrosion. All three of the aforementioned conditions must be present for hydrogen embrittlement to occur.
The left image shows a macroscopic view of a fractured, zincplated, steel bolt. In the presence of corrosive environments, hydrogen is generated at the austenitic weld metal cathode, which is capable of maintaining a high hydrogen content without cracking. Investigation of hydrogen embrittlement in 12cr2mo1rh steel. The hydrogen had only a small effect on the generalyield load, but it produced cracking along planes of high shear.
Effect of hydrogen on the intergranular stress corrosion. Commercial titanium can suffer intergranular stresscorrosion cracking see stress corrosion cracking in methanolic environments and red fuming nitric acid but otherwise it is immune to failure. Effects of hydrogen peroxide on intergranular stress. The hydrogen embrittlement of 12cr2mo1rh steel at different strain rates were investigated after hydrogen precharging for 4 h in a 0. Intergranular oxidation igo intergranular attack iga. Hydrogeninduced cracking an overview sciencedirect topics. Analysis of intergranular cracking in an alloy steel by hydrogenenhanced decohesion. Fracture mechanicsbased testing was used to quantify the stresscorrosion cracking and corrosion fatigue behavior of a precipitationhardened martensitic stainless steel custom 465h950 in full. This micrograph shows intergranular cracking caused by high temperature hydrogen attack in a c0. Highstrength carbon steel bolt failures due to hydrogen. Hydrogen absorption can also occur when a component is in service if the steel is exposed to acids or if corrosion of the steel occurs. Influence of impurity segregation on temper em brittlement. Analysis of intergranular cracking in an alloy steel by. No wonder steel can be susceptible to hydrogen cracking.
Hydrogen induced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Understanding and mitigating hydrogen embrittlement of steels. The consequence of igo and the concentration gradients that develop during oxide formation is that the material adjacent to the oxides has modified transformational behavior. Mcmahon suggested that interface decohesion at grainboundary carbides and precipitates is the mechanism of hydrogen assisted intergranular cracking, haic, in high strength steels. Corrosion evaluation of the pns citrox process for. Sem of fracture surfaces produced by subcritical cracking v 10. With regards to sour corrosion, the rate of hydrogen entry into the subsurface of a steel subject to sour corrosion is now well known to vary as h2s0.
Heat treatment baking was used to reduce hydrogen content. Caustic cracking are generally intergranular and bifurcate. The principal distinguishing feature of this type of crack is that it occurs in ferritic steels, most often immediately on welding or a short time after welding. A statistical, physicalbased, micromechanical model of hydrogeninduced intergranular fracture in steel p. Figure 1 conceptualized migration of hydrogen to the crack tip causing further cracking. A typical indication for this kind of damage is the branched cracks of fig. It involves the ingress of hydrogen into a component, an event that can seriously reduce the ductility and loadbearing capacity, cause cracking and catastrophic brittle failures at stresses below the yield stress of susceptible materials. The cracking of martensitic and precipitation hardened steel alloys is believed to be a form of hydrogen stress corrosion cracking that results from the entry into the metal of a portion of the atomic hydrogen. The embrittlement of of metal or alloy by atomic hydrogen involves the. Hydrogen cracking may also be called cold cracking or delayed cracking. Quasicleavage occurs where the crack initiates the stresses are highest, and the fracture changes to intergranular as the crack grows and relieves the hydrogen pressure. Hughes 1880 note on some effects produced by the immersion of steel and iron wires in acidulated water. This is a type of deterioration which can be linked to corrosion and corrosioncontrol processes.
Crack origin is at a flake at center of heavy section, sometimes in shrink zone. Intergranular cracking occurs when cracks form and grow along weakened grain boundaries in a metal. Intergranular wet hydrogen sulfide cracking journal. The required tensile stresses may be in the form of directly applied stresses or in the form of residual. He observed intergranular and transgranular failures, and he suggested they were caused by a reduction in strength of metalmetal bonds. Hydrogen cracking in metastable austenitic stainless. Intergranular fracture can occur in a wide variety of materials, including steel alloys, copper alloys, aluminum alloys, and ceramics.
When alloyed with oxygen or aluminum, transgranular stresscorrosion cracking can be induced in laboratory tests in seawater and. Delayed hydrogen assisted cracking hac crack morphology. Corrosionpedia what is hydrogeninduced cracking hic. A method of measuring the intergranular fracture strength.
Intergranular fracture an overview sciencedirect topics. Crack face covers entire section, coming to surface in a few locations. Mechanistic aspects of intergranular stress corrosion. Consequently, intergranular cracking observed at the lower temperature, that is, 408 k for type 304 and 316 steels is due to grain boundary martensiteinduced hydrogen embrittlement he and transgranular cracking for type 304 and 316 steels at higher temperatures at 416 and 428 k and for 310 steel is ascribed to stress corrosion cracking in. In this issue, the characteristic features and principal causes of hydrogen cracks are described. For example, the cracking morphology of austenitic stainless steel in 50% naoh solution has nothing to do with heat treatment, but is transgranular cracking. Johnson 1875 on some remarkable changes produced in iron and steels by the action of hydrogen acids. Igo is a surface phenomenon that is most often associated with atmosphere gas carburizing fig. Intergranular stress corrosion cracking an overview. Damage due to hydrogen embrittlement and stress corrosion. It involves atomic hydrogen, which is the smallest atom, that diffuses into a metallic structure. The photos above show the microstructure of a type 304 stainless steel. The phenomenon of hydrogeninduced intergranular brittle fracture of steels is a result of the combination of hydrogen dissolved in the crystal lattice and embrittling impurities that had.
More extensive use of the wet fluorescent magnetic particle technique in recent years as a refinery equipment inspection tool has. Steels were embrittled with hydrogen through cathodic charging. The figure on the left is the normalized microstructure and the one on the right is the sensitized structure and is susceptible to intergranular corrosion or intergranular stress corrosion cracking. Additionally, hydrogen embrittlement is a common category of embrittlement in which intergranular fracture can be observed. Fundamentals of hydrogen embrittlement in steel fasteners s. Hydrogeninduced cracking hic refers to the internal cracks brought about by material trapped in budding hydrogen atoms. Hydrogen embrittlement of steel industrial metallurgists.
Of these, hydrogen embrittlement is responsible for a. Ritchieb, a department of mechanical science and engineering, university of illinois at urbanachampaign, 1206 west green street, urbana, il 61801, usa b department of materials science and engineering, university of. A statistical, physicalbased, micromechanical model of. The primary objective of this study is to understand the interaction of hic with the grain structures and secondary microconstituents in x52 and x70 steel alloys. Similar effects have been seen with embrittled 4340 steel tested in hydrogen and hydrogen sulfide. Intergranular cracking is also known as intergranular corrosion, intergranular corrosion cracking, intergranular stress corrosion cracking igscc, intercrystalline corrosion, interdendritic corrosion or intergranular attack. Intergranular cracks are more likely to occur in the harder haz structures formed in low alloy and high carbon steels.
An example of failure due to hydrogen embrittlement is shown in the figures below. The most important hydrogen promoter industrially, and probably the most vigorous,2 is h2s, sour gas. Crack is straight, slightly jagged, in heavy section looks similar to quench crack crack face. In the case of a crystal lattice becoming saturated or coming into contact with atomic hydrogen, many alloys and metals may. Effects of hydrogen peroxide on intergranular stress corrosion cracking of stainless steel in high temperature water, i journal of nuclear science and technology. It occurs in carbon and lowalloyed steels exposed for an extended period to hydrogen under high pressure and at high temperature. Scanning electron microscopy image of intergranular hydrogen embrittlement mechanism.
Hydrogen embrittlement in highstrength steels simpson. Intergranular stress corrosion cracking of welded steel twi. How to avoid caustic cracking of carbon steel and low. A number of steps in the manufacturing stage can lead to hydrogen diffusion into the steel, with consideration of the possibility.
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